Make pidgin_set_custom_buddy_icon use the purple_buddy_icons_node_set_custom_icon_from_file convenience function. Also, I noticed that the custom buddy icons (which are set on contacts) were being converted according to the prpl icon specifications of whichever buddy in the contact was used in the pidgin_set_custom_buddy_icon call, since I have no earthly idea why we would want to do that I'm dropping it.